Normally you should be more concerned with the interface that the collection implements rather than its concrete type, i.e. you should think in terms of Seq, LinearSeq, and IndexedSeq rather than List, Array, and Vector, which are concrete implementations. So arguably there shouldn't be toList and toArray either, but I guess they're there because they're so fundamental.
The toIndexedSeq method in practice provides you with a Vector, unless a collection overrides this in order to provide a more efficient implementation. You can also make a Vector with Vector() ++ c where c is your collection.