Use raw strings:
x = r'\\dnassmb1\biloadfiles_dev\Workday'
This will prevent python from treating your backslashes as escape sequences. See string and byte literals in the Python documentation for a full treatment of string parsing.
It's important to pay close attention to the difference between representation and value here. Just because a string appears to have four backslashes in it, doesn't mean that those backslashes are in the value of the string. Consider:
>>> x = '\\dnassmb1\biloadfiles_dev\Workday' # regular string
>>> y = r'\\dnassmb1\biloadfiles_dev\Workday' # raw string
>>> print(x); print(y)
\dnassmbiloadfiles_dev\Workday
\\dnassmb1\biloadfiles_dev\Workday
Here, x and y are both just strings, once Python has parsed them. But even though the parts inside the quotes are the same, the bytes of the string are different. In y's case, you see exactly the number of backslashes you put in.