List(1,2,3) <= List(4,5)
is desugared to
list2ordered(List(1, 2, 3))(Predef.intWrapper) <= List(4, 5)
The signature of list2ordered
implicit def list2ordered[A](x: List[A])(implicit elem2ordered: A => Ordered[A]): Ordered[List[A]]
means that it's a conditional implicit conversion, namely, you have an implicit conversion List[A] => Ordered[List[A]] provided you have an implicit conversion A => Ordered[A].
And Predef.intWrapper is precisely such an implicit conversion because it's Int => RichInt and RichInt extends Ordered[Int] (RichInt <: ScalaNumberProxy[Int] <: OrderedProxy[Int] <: Ordered[Int]).
You can always see how implicits were resolved with reify
import scala.reflect.runtime.universe._
println(reify{List(1,2,3) <= List(4,5)}.tree)
//App.this.list2ordered(List.apply(1, 2, 3))(((x) => Predef.intWrapper(x))).$less$eq(List.apply(4, 5))