I have a Postgres 9.3 database which, by mistake, has been set to:

but I need it to be:

Since the Encoding doesn't change, it is safe to dump the DB and restore it later (see here) to a database with the new Collation / Character type?
I have a Postgres 9.3 database which, by mistake, has been set to:

but I need it to be:

Since the Encoding doesn't change, it is safe to dump the DB and restore it later (see here) to a database with the new Collation / Character type?
Perfectly safe -- the collation is just telling Postgres which set of rules to apply when sorting text.
You can even set it dynamically on a query basis in the order by clause, and should be able to alter it without needing to dump the database.