You are absolutely correct.But you got to bear in mind that when you use those as rvalues they are different.One has the type char, and can be used as an int as it is implicitly converted to the ASCII value, while the other has type char*.
Let me illustrate my point with a code if that helps:
int num='A'; //Valid, assigns 65 to num
char test=65; //Valid, as test will be 'A' after this
char *ptr="A" //Valid, assigns address of string "A" to pointer ptr
printf("%c,%d",'A','A'); // Output will be A,65
printf("%p",(void*)"A"); //Will print address where string "A" is
printf("%c","A"); ///WRONG
printf("%s","A"); //Works
Edit For the finer nuances, if you feel your understanding is up to that mark yet,refer to Mat's comment.Else read it after a few weeks when you have advanced further in your study of C.