The DapperRow object is designed to share a lot of state between rows. For example, if you fetch 40 rows, the column names etc are only stored once. If we used ExpandoObject, this would need to be configured per row. Hence, the use of DapperRow as the behind-the-scenes implementation detail is a deliberate efficiency thing.
Note that the object returned from the dynamic APIs can also be cast as IDictionary<string,object>.
I would, however, be open to supporting other types that support this dictionary usage - of which ExpandoObject is one. So yes, it could be changed such that:
var rows = conn.Query<ExpandoObject>(...);
works. It simply requires code to support it, and that code does not currently exist. So "no, but perhaps in a future build".
Note also that you don't need to use DapperRow at all... The more expected scenario is to use the generic API to materialize your own types.